Challenges
The rising demand for air travel has led to a 34% increase in direct CO2 emissions worldwide over the previous five years before the OVERLEAF project started. Aviation is forecast to be responsible for 24% of global emissions by 2050. As a result, the aviation industry must shift to new, low-carbon propulsion technologies and/or new fuels, such as hydrogen (H2).
The EU has identified H2 as a clean fuel. As such, H2 can help tackle climate change and reduce GHG emissions in a sector as important as aviation. Today’s industry, however, can’t move toward hydrogen-powered aircraft. The main challenge is the absence of viable H2 storage systems in aircraft, considering the strict limitations in weight, volume and cost-efficiency.
Hydrogen’s gravimetric energy density (GED) is three times greater than that of kerosene. This means aircraft would have to be redesigned to allow for larger tanks on board. The size and weight of H2 tanks pose major limitations for high energy demand on flights, thus reducing cost-effectiveness significantly for medium to long-range aircraft.
To respond to these needs, the OVERLEAF project has designed a disruptive low-pressure liquid H2 storage system (LPH), combining innovative functional and high-performance materials, thermal insulating materials and novel hydrogen leak detection sensors.
Our innovation
The design of the low-pressure, liquid hydrogen storage system architecture (LPH) combines new materials solutions, advanced and flexible manufacturing technologies, and sensors into an optimum configuration design. It is designed to improve the thermal performance of the storage tank, minimise the pressure inside the inner and the outer tanks and significantly reduce hydrogen leakage during in-service operation compared to SoA available LH2 storage solutions. In numbers, the OVERLEAF’s tank is able to contain 105kg of liquid hydrogen, at 23K and up to 6 bar of pressure, for 14 hours with a 2% loss of hydrogen.
The Inner Tank
The Inner Tank of the OVERLEAF project is designed to safely store liquid hydrogen, preventing leakage while maintaining cryogenic conditions.
REPLICABILITY
The manufacturing process of the tank may not be simple, but it is easily replicable, and even more so for minor-scale manufacturing. The main advantage of the process, however, is the flexibility: if additional ideas are to be incorporated, studied or tested, it is not only easy, but also much less expensive than other technologies.
SUSTAINABILITY
Additive manufacturing much reduces material waste, especially when it involves components as big as the ones involved. This is because the amount of material is (roughly) the one used for the part itself, in contrast with the conventional subtractive manufacturing methods such as machining, which would require a raw material billet, most of which would be wasted.
Open Cell Insulating Foam
An Open-Cell foam is an excellent choice for insulating a liquid hydrogen tank due to its unique structure and thermal properties.
INDUSTRIAL APPLICATIONS
A new generation of open cell foams are being developed. Thanks to their unique properties—lightweight structure, exceptional resistance to extremely low temperatures, and superior thermal insulation—these foams are expected to have a substantial impact. The supply chain will be impacted by new products and a new industrialisation process. This is focused on new markets that must be certified for the industry and for several sectors such as: Automotive, Aerospace, and Chemical and Environmental Industry.
MARKETABILITY
The development of advanced foams can have a significant economic and market impact depending on their properties, applications, and competitive advantages. In OVERLEAF project freeze-dried nanocellulose foams are reinforced with silica for cryogenic insulation in liquid hydrogen storage. These materials offer superior thermal insulation, reducing boil-off losses and lowering storage and transportation costs. Their lightweight structure contributes to improved fuel efficiency in hydrogen-powered vehicles and aerospace applications. With the growing hydrogen economy, demand for high-performance insulation materials is rising, creating opportunities for innovative solutions. Companies investing in these technologies can gain a competitive edge in the emerging clean energy market.
The Outer Tank
To advance hydrogen storage technology, a linerless composite tank has been developed for the OVERLEAF Outer Tank, using thermoplastic composites manufactured via the Automated Tape Laying (ATL) process.
SUSTAINABILITY
The polyamide 11 Rilsan® used as thermoplastic matrix, is being sourced from castor plants which makes it ecofriendly. The outer tank, manufactured using carbon fibre PA11 thermoplastic tapes, can be easily recycled at the end of life and the composite design aims to maximise the gravimetric density.
Closed Cell Insulating Foam
Supercritical carbon dioxide extrusion is a foaming process widely used to create polymer foams with the injection of CO2 in supercritical state in an extruder.
MARKETABILITY
The relatively low cost and availability of CO2 make the process economically viable, offering a competitive advantage over traditional foaming methods. Furthermore, the ability to fine-tune process parameters makes s-CO2 extrusion highly adaptable to a range of other applications.
SUSTAINABILITY
Unlike traditional chemical blowing agents, CO2 is non-toxic, non-flammable and can be recycled throughout the process, reducing the environmental footprint. The use of CO2 in its supercritical state allows for precise control over foam characteristics, such as cell size, density, and mechanical properties, offering a versatile and cost-effective method for producing polymer foams.
INDUSTRIAL APPLICATIONS
The thermal insulation process is especially beneficial in industries such as aerospace, where high-performance materials are required for insulation and structural applications; automotive, for lightweight, durable components; energy, particularly for energy-efficient storage solutions and thermal insulation; and packaging, where sustainable and highquality foams can reduce material use.
Hydrogen Sensors
Advanced fibre optic sensors using metal hydride thin films have been utilised for fast, precise hydrogen detection. These sensors offer high sensitivity, rapid response, and resilience in extreme conditions, ensuring safer and more efficient hydrogen use in aerospace applications.
INDUSTRIAL APPLICATIONS
These sensors offer exceptional versatility and can be seamlessly integrated into various hydrogen-dependent industries, including hydrogen-powered aviation, energy storage and industrial gas infrastructure.
SUSTAINABILITY
As the global demand for hydrogen technologies accelerates, the need for reliable and high-performance hydrogen sensors will grow significantly. This positions the technology as a critical enabler for the safe and sustainable adoption of hydrogen across the transport and energy sectors, ultimately contributing to a cleaner, zero-emission future.
UPSCALING
The sensors’ compact design, low power consumption, and scalability make them ideal for large-scale deployment, providing a cost-effective solution for real-time leak detection. Additionally, the spark-free operation enhances their safety profile, ensuring reliable monitoring in environments where conventional electrical sensors would pose a risk of ignition.
MARKETABILITY
The ability to manufacture these sensors using existing fabrication techniques, such as magnetron sputtering (a commercially available method for depositing thin films) and commercial fibre optic fabrication techniques, further boosts their replicability and mass production potential, driving down costs and facilitating widespread implementation.